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  6. Trimethylsilyl azide, 94%

Trimethylsilyl azide, 94%

Product Code. 11382685
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Product Code. 11382685 Supplier Thermo Scientific Alfa Aesar Supplier No. L00173.22
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Description

CAS: 4648-54-8 | C3H9N3Si | 115.21 g/mol

Trimethylsilyl azide is used as an azidonation reagent for amines, amides, aldehydes and ketones. It is involved in the preparation of alfa- and beta-siloxy azides from carbonyl compounds and epoxides. It is also used in the preparation of heterocyclic compounds and also acts as an effective substitute for hydrazoic acid. Further, it is used in the Oseltamivir total synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Trimethylsilyl azide is used as an azidonation reagent for amines, amides, aldehydes and ketones. It is involved in the preparation of alfa- and beta-siloxy azides from carbonyl compounds and epoxides. It is also used in the preparation of heterocyclic compounds and also acts as an effective substitute for hydrazoic acid. Further, it is used in the Oseltamivir total synthesis.

Solubility
Miscible with toluene, dichloromethane, diethyl ether and most organic solvents.

Notes
Moisture sensitive. Store in a cool place. Incompatible with strong oxidizing agents and strong acids.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 4648-54-8
Molecular Formula C3H9N3Si
Molecular Weight (g/mol) 115.21
MDL Number MFCD00001986
InChI Key SEDZOYHHAIAQIW-UHFFFAOYSA-N
Synonym trimethylsilyl azide, silane, azidotrimethyl, trimethylsilylazide, azido trimethyl silane, ccris 8048, tms azide, tms-azide, trimethyl silylazide, trimethylsilyl-azide, azido trimethylsilane
PubChem CID 78378
SMILES C[Si](C)(C)N=[N+]=[N-]

Specifications

Melting Point -95°C
Density 0.872
Boiling Point 95°C to 99°C
Flash Point 6°C (42°F)
Refractive Index 1.414
Quantity 100 g
UN Number UN1992
Beilstein 1903730
Sensitivity Moisture sensitive
Solubility Information Miscible with toluene,dichloromethane,diethyl ether and most organic solvents.
IUPAC Name azido(trimethyl)silane
Formula Weight 115.21
Percent Purity 94%
Chemical Name or Material Trimethylsilyl azide
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