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  7. Triisopropylsilane, 98%

Triisopropylsilane, 98%

Product Code. 11312157
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Product Code. 11312157 Supplier Thermo Scientific Alfa Aesar Supplier No. L09585.14
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Beskrivning

CAS: 6485-79-6 | C9H22Si | 158.36 g/mol

Triisopropylsilane is used as a protecting group in peptide synthesis and is also used as a reducing agent for the selective reduction of anomeric C-phenyl ketals. It is used in the selective silylation of primary hydroxyl groups without affecting the secondary hydroxyl group. It is used in the preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbine complex with high diastereoselectivity.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triisopropylsilane is used as a protecting group in peptide synthesis and is also used as a reducing agent for the selective reduction of anomeric C-phenyl ketals. It is used in the selective silylation of primary hydroxyl groups without affecting the secondary hydroxyl group. It is used in the preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbine complex with high diastereoselectivity.

Solubility
Immiscible with water.

Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong acids and strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Kemiska identifierare

CAS 6485-79-6
Molecular Formula C9H22Si
Molecular Weight (g/mol) 158.36
MDL Number MFCD00009657
InChI Key YDJXDYKQMRNUSA-UHFFFAOYSA-N
Synonym triisopropylsilane, tris propan-2-yl silane, triisopropyl silane, tri propan-2-yl silicon, tri-isopropylsilyl radical, triisopropylsilyl, tri-iso-propylsilane, ambotzrl-1102, pubchem12855
PubChem CID 6327611
SMILES CC(C)[SiH](C(C)C)C(C)C

Specifikationer

Boiling Point 166°C
Quantity 25 g
Linear Formula [(CH3)2CH]3SiH
UN Number UN1993
Beilstein 1733718
Flash Point 35°C (95°F)
Solubility Information Immiscible with water.
IUPAC Name tri(propan-2-yl)silicon
Formula Weight 158.36
Percent Purity 98%
Odor Mild
Refractive Index 1.434
Density 0.773
Chemical Name or Material Triisopropylsilane
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Produktbeteckning
  • Triisopropylsilane
 Signalord
  • Warning
 Riskkategorier
  • Serious eye damage/eye irritation Category 2
  • Flammable liquid Category 3
  • Skin corrosion/irritation Category 2
  • Specific target organ toxicity Category 3
 Faroangivelser
  • H226-Flammable liquid and vapour.
  • H315-Causes skin irritation.
  • H319-Causes serious eye irritation.
  • H335-May cause respiratory irritation.
 Skyddsangivelse
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
 Kompletterande information
  • MIXTURE LIST-Contains : Triisopropylsilane
SDS

RUO – Research Use Only

Produkttitel
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