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  5. (S)-(-)-4-Benzyl-2-oxazolidinone, 99%

(S)-(-)-4-Benzyl-2-oxazolidinone, 99%

Product Code. 11453767
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Product Code. 11453767 Supplier Thermo Scientific Alfa Aesar Supplier No. A18236.14
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Description

CAS: 90719-32-7 | C10H11NO2 | 177.20 g/mol

(S)-(-)-4-Benzyl-2-oxazolidinone is used in chiral auxiliary asymmetric alkylation. It has been used in the synthesis of (S)-equol. Preparation and functionalization of chiral, stabilized ylides. It was used for asymmetric synthesis of (3R)- and (3S)-piperazic acid.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(S)-(-)-4-Benzyl-2-oxazolidinone is used in chiral auxiliary asymmetric alkylation. It has been used in the synthesis of (S)-equol. Preparation and functionalization of chiral, stabilized ylides. It was used for asymmetric synthesis of (3R)- and (3S)-piperazic acid.

Solubility
Insoluble in water.

Notes
Hygroscopic. Incompatible with oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 90719-32-7
Molecular Formula C10H11NO2
Molecular Weight (g/mol) 177.20
MDL Number MFCD00064496
InChI Key OJOFMLDBXPDXLQ-VIFPVBQESA-N
Synonym s-4-benzyl-2-oxazolidinone, s-4-benzyloxazolidin-2-one, 4s-4-benzyl-1,3-oxazolidin-2-one, s---4-benzyl-2-oxazolidinone, s-4-benzyl-oxazolidin-2-one, 2-oxazolidinone, 4-phenylmethyl-, 4s, s-+-4-benzyl-2-oxazolidinone, s-4-phenylmethyl-2-oxazolidinone, 4s-4-phenylmethyl-1,3-oxazolidin-2-one
PubChem CID 736225
IUPAC Name (4S)-4-benzyl-1,3-oxazolidin-2-one
SMILES O=C1N[C@@H](CC2=CC=CC=C2)CO1

Specifications

Melting Point 87°C to 89°C
Beilstein 3649667
Solubility Information Insoluble in water.
Quantity 25 g
Formula Weight 177.2
Optical Rotation −64° (c=1 in Chloroform)
Sensitivity Hygroscopic
Percent Purity 99%
Chemical Name or Material (S)-(-)-4-Benzyl-2-oxazolidinone

Safety and Handling

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Signal Word
  • Warning
 Hazard Category
  • Acute toxicity Category 4
  • Specific target organ toxicity after repeated exposure Category 2
 Hazard Statement
  • H302-Harmful if swallowed.
  • H373-May cause damage to organs.
 Precautionary Statement
  • P260-Do not breathe dust/fume/gas/mist/vapours/spray.
  • P264-Wash thoroughly after handling.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P312-Call a POISON CENTER/doctor/if you feel unwell.
SDS

RUO – Research Use Only

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