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  8. Phenyl chloroformate, 99%

Phenyl chloroformate, 99%

Product Code. 11444040
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Artikelnummer. 11444040

Marke: Thermo Scientific Alfa Aesar A12618.22

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Beschreibung

CAS: 1885-14-9 | C7H5ClO2 | 156.57 g/mol

Phenyl chloroformate is used in the synthesis of poly(2-(phenoxycarbonyloxy)ethyl methacrylate) and phenyl-(4-vinylphenyl) carbonate. It acts as a precursor of phenyl mixed anhydrides which are used in peptide coupling reactions. It serves as a dehydrating reagent for the conversion of primary amides to nitriles and an intermediate in the synthesis of pharmaceuticals and carbamates.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Phenyl chloroformate is used in the synthesis of poly(2-(phenoxycarbonyloxy)ethyl methacrylate) and phenyl-(4-vinylphenyl) carbonate. It acts as a precursor of phenyl mixed anhydrides which are used in peptide coupling reactions. It serves as a dehydrating reagent for the conversion of primary amides to nitriles and an intermediate in the synthesis of pharmaceuticals and carbamates.

Solubility
Miscible with N,N-dimethylformamide.

Notes
Store in cool place. Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with bases, alcohols and amines. Hydrolyses in water.

Chemische Identifikatoren

CAS 1885-14-9
Molecular Formula C7H5ClO2
Molecular Weight (g/mol) 156.57
MDL Number MFCD00000637
InChI Key AHWALFGBDFAJAI-UHFFFAOYSA-N
Synonym phenyl chloroformate, chloroformic acid phenyl ester, phenyl chlorocarbonate, carbonochloridic acid, phenyl ester, phenoxycarbonyl chloride, formic acid, chloro-, phenyl ester, fenylester kyseliny chlormravenci, phenylchloroformate, unii-6tnd0d6d3y, 6tnd0d6d3y
PubChem CID 15891
IUPAC Name phenyl carbonochloridate
SMILES ClC(=O)OC1=CC=CC=C1

Spezifikation

Melting Point -38°C
Density 1.246
Boiling Point 188°C to 189°C
Flash Point 76°C (169°F)
Refractive Index 1.511
Quantity 100 g
UN Number UN2746
Beilstein 606778
Sensitivity Moisture sensitive
Solubility Information Miscible with N,N-dimethylformamide.
Formula Weight 156.57
Percent Purity 99%
Chemical Name or Material Phenyl chloroformate
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Sicherheit und Handhabung

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Produktidentifikator
  • Phenyl chloroformate
 Signalwort
  • Danger
 Gefahrenkategorie
  • Acute toxicity Category 2
  • Acute toxicity Category 4
  • LONG-TERM AQUATIC HAZARD Chronic 3
  • Serious eye damage/eye irritation Category 1
  • Substances and mixtures corrosive to metals Category 1
  • Skin corrosion/irritation Category 1 C
  • Specific target organ toxicity Category 3
 Gefahrenhinweis
  • H290-May be corrosive to metals.
  • H302-Harmful if swallowed.
  • H314-Causes severe skin burns and eye damage.
  • H318-Causes serious eye damage.
  • H330-Fatal if inhaled.
  • H335-May cause respiratory irritation.
  • H412-Harmful to aquatic life with long lasting effects.
 Sicherheitshinweis
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P310-Immediately call a POISON CENTER/doctor/.
 Ergänzende Informationen
  • MIXTURE LIST-Contains : Phenyl chloroformate
Sicherheitsdatenblatt (SDS)

RUO – Research Use Only

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