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  6. mu-Chloro-mu-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene

mu-Chloro-mu-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene

Product Code. 11415230
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Product Code. 11415230 Supplier Thermo Scientific Alfa Aesar Supplier No. 044506.AA
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Estimated Shipment: 11-08-2026
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Description

CAS: 67719-69-1 | C13H18AlClTi

μ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum is used in organic synthesis for carbonyl methylenation, A versatile methylenation reagent for the conversion of ketones and aldehydes to olefins, it offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers. Tebbe reagent can be used to olefinate aldehydes, to methylenate a chiral polyhydroxyketone with high diasteroselctivity.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

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Chemical Identifiers

CAS 67719-69-1
Molecular Formula C13H18AlClTi
MDL Number MFCD00151575
Synonym Tebbe Reagent

Specifications

Color Brown-Red
Density 0.927 g/mL
Flash Point 1°C (34°F)
Quantity 5 mL
UN Number UN3399
Sensitivity Air and moisture sensitive
Merck Index 14,9091
Solubility Information Soluble in toluene,benzene,dichloromethane. Insoluble in water.
Formula Weight 284.62
Physical Form Liquid
Chemical Name or Material mu-Chloro-mu-methylenebis (cyclopentadienyl)titaniumdimethylaluminum
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RUO – Research Use Only

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