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  8. Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)

Product Code. 15496635
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Product Code. 15496635

Brand: Thermo Scientific Alfa Aesar 044955.03

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Description

CAS: 16971-33-8 | C55H46ClOP3Ru | 952.41 g/mol

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR).

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 16971-33-8
Molecular Formula C55H46ClOP3Ru
Molecular Weight (g/mol) 952.41
MDL Number MFCD00049804
InChI Key IMPHYUNMDWWJAH-UHFFFAOYSA-M
Synonym carbonylchlorohydridotris triphenylphosphine-ruthenium ii
PubChem CID 71463878
IUPAC Name formaldehyde;hydride;ruthenium(2+);triphenylphosphane;chloride
SMILES Cl[RuH++].[C-]#[O+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point 204°C to 206°C (decomposition)
Color Gray
Linear Formula [(C6H5)3P]3Ru(CO)(Cl)H
Quantity 1 g
Sensitivity Light sensitive; Very Hygroscopic
Solubility Information Insoluble in water,ethanol,and DMSO. Sparingly soluble in benzene,chloroform and acetone.
Formula Weight 952.41
Physical Form Crystalline
Chemical Name or Material Carbonylchlorohydridotris (triphenylphosphine)ruthenium (II)

Safety and Handling

compliance-icons
Product Identifier
  • Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
 Signal Word
  • Warning
 Hazard Category
  • Acute toxicity Category 4
  • Serious eye damage/eye irritation Category 2
  • Skin corrosion/irritation Category 2
  • Specific target organ toxicity Category 3
 Hazard Statement
  • H302-Harmful if swallowed.
  • H312-Harmful in contact with skin.
  • H315-Causes skin irritation.
  • H319-Causes serious eye irritation.
  • H332-Harmful if inhaled.
  • H335-May cause respiratory irritation.
 Precautionary Statement
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P312-Call a POISON CENTER/doctor/if you feel unwell.
 Supplemental information
  • MIXTURE LIST-Contains : Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II)
SDS

RUO – Research Use Only

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