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Bis(1,5-cyclooctadiene)nickel(0)

Product Code. 15421527
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10 g
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Product Code. 15421527

Brand: Thermo Scientific Alfa Aesar 039234.09

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Description

CAS: 1295-35-8 | C16H24Ni | 275.06 g/mol

Bis(1,5-cyclooctadiene)nickel(0) is used as a catalyst for the cycloaddition of 1,3-dienes and is used to catalyze the addition of allyl phenyl sulfide to alkynes leading to 1,4-dienes. Also, it is involved as a catalyst for asymmetric alpha-arylation and heteroarylation of ketones with chloroarenes, stereoselective borylative ketone-diene coupling, cycloaddition of benzamides with internal alkynes and methyl carboxylation of homopropargylic alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 1295-35-8
Molecular Formula C16H24Ni
Molecular Weight (g/mol) 275.06
MDL Number MFCD00058902
InChI Key JRTIUDXYIUKIIE-KZUMESAESA-N
Synonym bis 1,5-cyclooctadiene nickel 0, bis 1,5-cyclooctadiene nickel, ni cod 2, ccris 5973, bis cyclooctadiene nickel 0, nickel, bis 1,5-cyclooctadiene, bis cyclooctadiene nickel, 1z,5z-cycloocta-1,5-diene; nickel, nickel biscod, pubchem16018
PubChem CID 6433264
SMILES [Ni].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1

Specifications

Melting Point 60°C (decomposition)
Color Yellow
Odor Odorless
Quantity 10 g
UN Number UN1325
Sensitivity Air and light sensitive
Solubility Information Soluble in benzene,toluene,terahydrofuran,ether,dimethyl formamide,hexamethylphosphoramide,N-methylpyrrolidinone. Insoluble in water.
IUPAC Name (1Z,5Z)-cycloocta-1,5-diene;nickel
Formula Weight 275.06
Physical Form Crystalline
Chemical Name or Material Bis(1,5-cyclooctadiene)nickel(0)
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