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  6. Bis(1,5-cyclooctadiene)nickel(0), 96%

Bis(1,5-cyclooctadiene)nickel(0), 96%

Product Code. 11490680
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Quantity:
2 g
10 g
Unit Size:
10g
2g
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Product Code. 11490680

Brand: Thermo Scientific Alfa Aesar 044157.09

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Description

CAS: 1295-35-8 | C16H24Ni | 275.06 g/mol

Catalyst for isomerization and hydrosilyltion of unsaturated compounds. Co-catalyst for oligomerization/cyclooligomerization or polymerization of alkenes, Bis(1,5-cyclooctadiene)nickel(0) is used as a catalyst for the cycloaddition of 1,3-dienes and used to catalyze the addition of allyl phenyl sulfide to alkynes leading to 1,4-dienes. It is involved as a catalyst for asymmetric alpha-arylation and heteroarylation of ketones with chloroarenes, stereoselective borylative ketone-diene coupling, cycloaddition of benzamides with internal alkynes and methyl carboxylation of homopropargylic alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

  • Catalyst for isomerization and hydrosilyltion of unsaturated compounds
  • Co-catalyst for oligomerization/cyclooligomerization or polymerization of alkenes, butadiene
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 1295-35-8
Molecular Formula C16H24Ni
Molecular Weight (g/mol) 275.06
MDL Number MFCD00058902
InChI Key JRTIUDXYIUKIIE-KZUMESAESA-N
Synonym bis 1,5-cyclooctadiene nickel 0, bis 1,5-cyclooctadiene nickel, ni cod 2, ccris 5973, bis cyclooctadiene nickel 0, nickel, bis 1,5-cyclooctadiene, bis cyclooctadiene nickel, 1z,5z-cycloocta-1,5-diene; nickel, nickel biscod, pubchem16018
PubChem CID 6433264
IUPAC Name (1Z,5Z)-cycloocta-1,5-diene;nickel
SMILES [Ni].C1C\C=C/CC\C=C/1.C1C\C=C/CC\C=C/1

Specifications

Melting Point 60°C (decomposition)
Color Yellow
Odor Odorless
Quantity 10 g
UN Number UN1325
Sensitivity Air and light sensitive
Solubility Information Soluble in benzene,toluene,terahydrofuran,ether,dimethyl formamide,hexamethylphosphoramide,N-methylpyrrolidinone. Insoluble in water.
Formula Weight 275.06
Percent Purity 96%
Physical Form Powder
Chemical Name or Material Bis (1,5-cyclooctadiene)nickel (0)
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Safety and Handling

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Product Identifier
  • Bis(1,5-cyclooctadiene)nickel(0)
 Signal Word
  • Danger
 Hazard Category
  • Carcinogenicity Category 1B
  • Flammable solid Category 2
  • Skin sensitiser Category 1
 Hazard Statement
  • H228-Flammable solid.
  • H317-May cause an allergic skin reaction.
  • H350-May cause cancer.
 Precautionary Statement
  • P201-Obtain special instructions before use.
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P308+P313-IF exposed or concerned: Get medical advice/attention.
  • P370+P378-In case of fire: Use dry sand, dry chemical, or alcohol-resistant foam to extinguish.
 Supplemental information
  • MIXTURE LIST-Contains : Bis(1,5-cyclooctadiene)nickel
SDS

RUO – Research Use Only

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