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Phenylphosphines and derivatives

Organophosphorus compounds that consist of a phenyl group with a phosphine group substitution in the following structure: C₆H₅PH₂; phospine groups have a phosphorus atom bonded to three hydrogen atoms. They are the phosphorus analog of aniline.
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1

Tris[4-(trifluoromethyl)phenyl]phosphine, 98%

CAS: 13406-29-6 Molecular Formula: C21H12F9P Molecular Weight (g/mol): 466.286 MDL Number: MFCD00058883 InChI Key: PXYCJKZSCDFXLR-UHFFFAOYSA-N Synonym: tris 4-trifluoromethylphenyl phosphine,tris 4-trifluoromethyl phenyl phosphine,tris 4-trifluoromethyl phenyl phosphane,phosphine, tris 4-trifluoromethyl phenyl,tris p-trifluoromethylphenyl phosphine,phosphine, tris .alpha.,.alpha.,.alpha.-trifluoro-p-tolyl,tris p-trifluoromethylphenyl phosphine,min,acmc-20ajbq PubChem CID: 139448 IUPAC Name: tris[4-(trifluoromethyl)phenyl]phosphane SMILES: C1=CC(=CC=C1C(F)(F)F)P(C2=CC=C(C=C2)C(F)(F)F)C3=CC=C(C=C3)C(F)(F)F

PubChem CID 139448
CAS 13406-29-6
Molecular Weight (g/mol) 466.286
MDL Number MFCD00058883
SMILES C1=CC(=CC=C1C(F)(F)F)P(C2=CC=C(C=C2)C(F)(F)F)C3=CC=C(C=C3)C(F)(F)F
Synonym tris 4-trifluoromethylphenyl phosphine,tris 4-trifluoromethyl phenyl phosphine,tris 4-trifluoromethyl phenyl phosphane,phosphine, tris 4-trifluoromethyl phenyl,tris p-trifluoromethylphenyl phosphine,phosphine, tris .alpha.,.alpha.,.alpha.-trifluoro-p-tolyl,tris p-trifluoromethylphenyl phosphine,min,acmc-20ajbq
IUPAC Name tris[4-(trifluoromethyl)phenyl]phosphane
InChI Key PXYCJKZSCDFXLR-UHFFFAOYSA-N
Molecular Formula C21H12F9P
2

Tris(4-trifluoromethylphenyl)phosphine, 99%

CAS: 13406-29-6 Molecular Formula: C21H12F9P Molecular Weight (g/mol): 466.29 MDL Number: MFCD00058883 InChI Key: PXYCJKZSCDFXLR-UHFFFAOYSA-N Synonym: tris 4-trifluoromethylphenyl phosphine,tris 4-trifluoromethyl phenyl phosphine,tris 4-trifluoromethyl phenyl phosphane,phosphine, tris 4-trifluoromethyl phenyl,tris p-trifluoromethylphenyl phosphine,phosphine, tris .alpha.,.alpha.,.alpha.-trifluoro-p-tolyl,tris p-trifluoromethylphenyl phosphine,min,acmc-20ajbq PubChem CID: 139448 IUPAC Name: tris[4-(trifluoromethyl)phenyl]phosphane SMILES: C1=CC(=CC=C1C(F)(F)F)P(C2=CC=C(C=C2)C(F)(F)F)C3=CC=C(C=C3)C(F)(F)F

PubChem CID 139448
CAS 13406-29-6
Molecular Weight (g/mol) 466.29
MDL Number MFCD00058883
SMILES C1=CC(=CC=C1C(F)(F)F)P(C2=CC=C(C=C2)C(F)(F)F)C3=CC=C(C=C3)C(F)(F)F
Synonym tris 4-trifluoromethylphenyl phosphine,tris 4-trifluoromethyl phenyl phosphine,tris 4-trifluoromethyl phenyl phosphane,phosphine, tris 4-trifluoromethyl phenyl,tris p-trifluoromethylphenyl phosphine,phosphine, tris .alpha.,.alpha.,.alpha.-trifluoro-p-tolyl,tris p-trifluoromethylphenyl phosphine,min,acmc-20ajbq
IUPAC Name tris[4-(trifluoromethyl)phenyl]phosphane
InChI Key PXYCJKZSCDFXLR-UHFFFAOYSA-N
Molecular Formula C21H12F9P
3

(4-Methoxycarbonylbenzyl)triphenylphosphonium chloride, 97%

CAS: 1253-47-0 Molecular Formula: C27H24ClO2P Molecular Weight (g/mol): 446.91 MDL Number: MFCD02683069 InChI Key: NKKAHXNONUTMEY-UHFFFAOYSA-M Synonym: 4-methoxycarbonylbenzyl triphenylphosphonium chloride,4-methoxycarbonyl-benzyltriphenylphosphoniumchloride,4-methoxycarbonyl benzyl triphenylphosphonium chloride,4-carbomethoxybenzyl triphenylphosphonium chloride,methyl 4-triphenylphosphino methyl benzoate, chloride,acmc-1btgg,4-methoxycarbonyl-benzyltriphenylphosphonium chloride,methyl alpha triphenylphosphonio-p-toluate chloride,4-methoxycarbonyl-benzyl-triphenyl-phosphonium chloride PubChem CID: 18001058 IUPAC Name: (4-methoxycarbonylphenyl)methyl-triphenylphosphanium;chloride SMILES: [Cl-].COC(=O)C1=CC=C(C[P+](C2=CC=CC=C2)(C2=CC=CC=C2)C2=CC=CC=C2)C=C1

PubChem CID 18001058
CAS 1253-47-0
Molecular Weight (g/mol) 446.91
MDL Number MFCD02683069
SMILES [Cl-].COC(=O)C1=CC=C(C[P+](C2=CC=CC=C2)(C2=CC=CC=C2)C2=CC=CC=C2)C=C1
Synonym 4-methoxycarbonylbenzyl triphenylphosphonium chloride,4-methoxycarbonyl-benzyltriphenylphosphoniumchloride,4-methoxycarbonyl benzyl triphenylphosphonium chloride,4-carbomethoxybenzyl triphenylphosphonium chloride,methyl 4-triphenylphosphino methyl benzoate, chloride,acmc-1btgg,4-methoxycarbonyl-benzyltriphenylphosphonium chloride,methyl alpha triphenylphosphonio-p-toluate chloride,4-methoxycarbonyl-benzyl-triphenyl-phosphonium chloride
IUPAC Name (4-methoxycarbonylphenyl)methyl-triphenylphosphanium;chloride
InChI Key NKKAHXNONUTMEY-UHFFFAOYSA-M
Molecular Formula C27H24ClO2P
4

2-(Triphenylphosphoranylidene)propionaldehyde, 98%

CAS: 24720-64-7 Molecular Formula: C21H19OP Molecular Weight (g/mol): 318.36 MDL Number: MFCD00075596 InChI Key: VHUQEFAWBCDBSC-UHFFFAOYSA-N Synonym: 2-triphenylphosphoranylidene propionaldehyde,2-triphenylphosphoranylidene propanal,propanal, 2-triphenylphosphoranylidene,1-formylethylidenetriphenylphosphorane,2-triphenyl-??-phosphanylidene propanal,acmc-20aol9,2-triphenylylidene propanal,1-formylethylidene triphenyl phosphorane,alpha-formylethylidenetriphenylphosphorane,propanal,2-triphenylphosphoranylidene PubChem CID: 4280987 IUPAC Name: 2-(triphenyl-$l^{5}-phosphanylidene)propanal SMILES: CC(C=O)=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

PubChem CID 4280987
CAS 24720-64-7
Molecular Weight (g/mol) 318.36
MDL Number MFCD00075596
SMILES CC(C=O)=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
Synonym 2-triphenylphosphoranylidene propionaldehyde,2-triphenylphosphoranylidene propanal,propanal, 2-triphenylphosphoranylidene,1-formylethylidenetriphenylphosphorane,2-triphenyl-??-phosphanylidene propanal,acmc-20aol9,2-triphenylylidene propanal,1-formylethylidene triphenyl phosphorane,alpha-formylethylidenetriphenylphosphorane,propanal,2-triphenylphosphoranylidene
IUPAC Name 2-(triphenyl-$l^{5}-phosphanylidene)propanal
InChI Key VHUQEFAWBCDBSC-UHFFFAOYSA-N
Molecular Formula C21H19OP
5

3-(Triphenylphosphoranylidene)dihydrofuran-2-(3H)-one, 97%, Thermo Scientific™

CAS: 34932-07-5 Molecular Formula: C22H19O2P Molecular Weight (g/mol): 346.37 MDL Number: MFCD00065318 InChI Key: JUKRJGQYUNADDD-UHFFFAOYSA-N Synonym: 2 3h-furanone, 3-triphenylphosphoranylidene,gamma-butyrolactonylidene triphenyl phosphorane,2-triphenylphosphoranylidene-gamma-butyrolactone,alpha-triphenylphosphoranylidene-gamma-butyrolactone,2 3h-furanone, dihydro-3-triphenylphosphoranylidene,3-triphenylphosphoranylidene dihydro-2 3h-furanone,3-triphenyl-??-phosphanylidene oxolan-2-one,3-triphenyl-,e5-phosphanylidene dihydrofuran-2 3h-one,.gamma.-butyrolactonylidene triphenyl phosphorane,2-oxotetrahydrofuran-3-ylidenetriphenylphosphorane PubChem CID: 97111 IUPAC Name: 3-(triphenyl-$l^{5}-phosphanylidene)oxolan-2-one SMILES: O=C1OCCC1=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

PubChem CID 97111
CAS 34932-07-5
Molecular Weight (g/mol) 346.37
MDL Number MFCD00065318
SMILES O=C1OCCC1=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
Synonym 2 3h-furanone, 3-triphenylphosphoranylidene,gamma-butyrolactonylidene triphenyl phosphorane,2-triphenylphosphoranylidene-gamma-butyrolactone,alpha-triphenylphosphoranylidene-gamma-butyrolactone,2 3h-furanone, dihydro-3-triphenylphosphoranylidene,3-triphenylphosphoranylidene dihydro-2 3h-furanone,3-triphenyl-??-phosphanylidene oxolan-2-one,3-triphenyl-,e5-phosphanylidene dihydrofuran-2 3h-one,.gamma.-butyrolactonylidene triphenyl phosphorane,2-oxotetrahydrofuran-3-ylidenetriphenylphosphorane
IUPAC Name 3-(triphenyl-$l^{5}-phosphanylidene)oxolan-2-one
InChI Key JUKRJGQYUNADDD-UHFFFAOYSA-N
Molecular Formula C22H19O2P
8

Alfa Aesar™ Isobutyltriphenylphosphonium bromide, 98+%, Thermo Scientific™

CAS: 22884-29-3 Molecular Formula: C22H24BrP Molecular Weight (g/mol): 399.31 MDL Number: MFCD00031593 InChI Key: VIKPDPHNYHUZQW-UHFFFAOYSA-M Synonym: isobutyltriphenylphosphonium bromide,2-methylpropyl triphenyl phosphanium bromide,phosphonium, 2-methylpropyl triphenyl-, bromide,2-methylpropyl triphenylphosphanium bromide,acmc-1citv,isobutyltriphenylphosphoniumbromide,isobutyl triphenylphosphonium bromide,2-methylpropyl triphenyl phosphonium bromide,isobutyl triphenyl phosphonium bromide,phosphonium, 2-methylpropyl triphenyl-,bromide 1:1 PubChem CID: 2724571 SMILES: [Br-].CC(C)C[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

PubChem CID 2724571
CAS 22884-29-3
Molecular Weight (g/mol) 399.31
MDL Number MFCD00031593
SMILES [Br-].CC(C)C[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
Synonym isobutyltriphenylphosphonium bromide,2-methylpropyl triphenyl phosphanium bromide,phosphonium, 2-methylpropyl triphenyl-, bromide,2-methylpropyl triphenylphosphanium bromide,acmc-1citv,isobutyltriphenylphosphoniumbromide,isobutyl triphenylphosphonium bromide,2-methylpropyl triphenyl phosphonium bromide,isobutyl triphenyl phosphonium bromide,phosphonium, 2-methylpropyl triphenyl-,bromide 1:1
InChI Key VIKPDPHNYHUZQW-UHFFFAOYSA-M
Molecular Formula C22H24BrP
9

Thermo Scientific Alfa Aesar Propargyltriphenylphosphonium bromide, 97%, Thermo Scientific™

CAS: 2091-46-5 Molecular Formula: C21H18BrP Molecular Weight (g/mol): 381.25 MDL Number: MFCD00011811 InChI Key: AFZDAWIXETXKRE-UHFFFAOYSA-M Synonym: triphenylpropargylphosphonium bromide,propargyltriphenylphosphonium bromide,prop-2-ynyltriphenylphosphonium bromide,triphenyl prop-2-yn-1-yl phosphonium bromide,propargyl triphenylphosphonium bromide,acmc-1cbag,propargyltriphenylphosphoniumbromide,triphenylpropargylphosphoniumbromide,triphenylprop-2-ynylphosphine, bromide,triphenyl-2-propynylphosphonium bromide PubChem CID: 2724214 SMILES: [Br-].C#CC[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

PubChem CID 2724214
CAS 2091-46-5
Molecular Weight (g/mol) 381.25
MDL Number MFCD00011811
SMILES [Br-].C#CC[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
Synonym triphenylpropargylphosphonium bromide,propargyltriphenylphosphonium bromide,prop-2-ynyltriphenylphosphonium bromide,triphenyl prop-2-yn-1-yl phosphonium bromide,propargyl triphenylphosphonium bromide,acmc-1cbag,propargyltriphenylphosphoniumbromide,triphenylpropargylphosphoniumbromide,triphenylprop-2-ynylphosphine, bromide,triphenyl-2-propynylphosphonium bromide
InChI Key AFZDAWIXETXKRE-UHFFFAOYSA-M
Molecular Formula C21H18BrP
10

Thermo Scientific Alfa Aesar (2-Carboxyethyl)triphenylphosphonium tribromide, 98+%, Thermo Scientific™

CAS: 55985-85-8 Molecular Formula: C22H24BrO2P Molecular Weight (g/mol): 431.31 MDL Number: MFCD00051883 InChI Key: MBIJNKFEWFACKA-UHFFFAOYSA-N Synonym: 2-carboxyethyl triphenylphosphanium tribromide PubChem CID: 57350967 IUPAC Name: 2-carboxyethyl(triphenyl)phosphanium;tribromide SMILES: C.[Br-].OC(=O)CC[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1

PubChem CID 57350967
CAS 55985-85-8
Molecular Weight (g/mol) 431.31
MDL Number MFCD00051883
SMILES C.[Br-].OC(=O)CC[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
Synonym 2-carboxyethyl triphenylphosphanium tribromide
IUPAC Name 2-carboxyethyl(triphenyl)phosphanium;tribromide
InChI Key MBIJNKFEWFACKA-UHFFFAOYSA-N
Molecular Formula C22H24BrO2P
11

(S)-(-)-1-[2-(Diphenylphosphino)phenyl]ethylamine, 97+%

CAS: 913196-43-7 Molecular Formula: C20H20NP Molecular Weight (g/mol): 305.36 MDL Number: MFCD17013987 InChI Key: KPFJIPHGQGHIMM-XISACWJONA-N Synonym: s-1-2-diphenylphosphino phenyl ethanamine,s-1-2-diphenylphosphino phenyl ethylamine,s---1-2-diphenylphosphino phenyl ethylamine,1s-1-2-diphenylphosphanyl phenyl ethanamine,2-1-aminoethyl triphenylphosphine,s-alpha-methyl-2-diphenylphosphino benzylamine,s-1-2-diphenylphosphanyl phenyl ethan-1-amine,1s-1-2-diphenylphosphanyl phenyl ethan-1-amine PubChem CID: 57514668 IUPAC Name: (1S)-1-(2-diphenylphosphanylphenyl)ethanamine SMILES: C[C@H](N)C1=CC=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1

PubChem CID 57514668
CAS 913196-43-7
Molecular Weight (g/mol) 305.36
MDL Number MFCD17013987
SMILES C[C@H](N)C1=CC=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1
Synonym s-1-2-diphenylphosphino phenyl ethanamine,s-1-2-diphenylphosphino phenyl ethylamine,s---1-2-diphenylphosphino phenyl ethylamine,1s-1-2-diphenylphosphanyl phenyl ethanamine,2-1-aminoethyl triphenylphosphine,s-alpha-methyl-2-diphenylphosphino benzylamine,s-1-2-diphenylphosphanyl phenyl ethan-1-amine,1s-1-2-diphenylphosphanyl phenyl ethan-1-amine
IUPAC Name (1S)-1-(2-diphenylphosphanylphenyl)ethanamine
InChI Key KPFJIPHGQGHIMM-XISACWJONA-N
Molecular Formula C20H20NP