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(+)-DIOP, 98%, Thermo Scientific™

Catalog Number p-7025508
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Quantity:
0.25 g
1 g
This item is not returnable. View return policy
37002-48-5
C31H32O2P2
498.543
MFCD00009760
VCHDBLPQYJAQSQ-LOYHVIPDSA-N
+-diop, unii-5p52k0ij7t, 4s,5s-2,2-dimethyl-1,3-dioxolane-4,5-diyl bis methylene bis diphenylphosphine, s,s-diop, 4s,5s-+-4,5-bis diphenylphosphinomethyl-2,2-dimethyl-1,3-dioxolane, 2s,3s-+-1,4-bis diphenylphosphino-2,3-o-isopropylidene-2,3-butanediol, 4s,5s-+-bis diphenylphosphinomethyl-2,2-dimethyl-1,3-dioxolane, 4s,5s-4,5-bis diphenylphosphinomethyl-2,2-dimethyl-1,3-dioxolane, +-1,4-bis diphenylphosphino-1,4-dideoxy-2,3-o-isopropylidene-d-threitol, 2s,3s-+-2,3-o-isopropylidene-2,3-dihydroxy-1,4-bis diphenylphosphino butane
3084647
[(4S,5S)-5-(diphenylphosphanylmethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl-diphenylphosphane
CC1(OC(C(O1)CP(C2=CC=CC=C2)C3=CC=CC=C3)CP(C4=CC=CC=C4)C5=CC=CC=C5)C
This item is not returnable. View return policy
37002-48-5
C31H32O2P2
498.543
MFCD00009760
VCHDBLPQYJAQSQ-LOYHVIPDSA-N
+-diop, unii-5p52k0ij7t, 4s,5s-2,2-dimethyl-1,3-dioxolane-4,5-diyl bis methylene bis diphenylphosphine, s,s-diop, 4s,5s-+-4,5-bis diphenylphosphinomethyl-2,2-dimethyl-1,3-dioxolane, 2s,3s-+-1,4-bis diphenylphosphino-2,3-o-isopropylidene-2,3-butanediol, 4s,5s-+-bis diphenylphosphinomethyl-2,2-dimethyl-1,3-dioxolane, 4s,5s-4,5-bis diphenylphosphinomethyl-2,2-dimethyl-1,3-dioxolane, +-1,4-bis diphenylphosphino-1,4-dideoxy-2,3-o-isopropylidene-d-threitol, 2s,3s-+-2,3-o-isopropylidene-2,3-dihydroxy-1,4-bis diphenylphosphino butane
3084647
[(4S,5S)-5-(diphenylphosphanylmethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl-diphenylphosphane
CC1(OC(C(O1)CP(C2=CC=CC=C2)C3=CC=CC=C3)CP(C4=CC=CC=C4)C5=CC=CC=C5)C

This Thermo Scientific brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific.

Applications
It is employed as a ligand for the in situ preparation of chiral hydrogenation catalysts. It also finds it application for the in situ preparation of chiral hydrogenation catalysts, ligand for Rh(I)-catalyzed asymmetric hydrogenation of enamides, 1,4-disilylation of α,β-unsaturated ketones, Heck reaction of alkenyl iodides, and hydroformylation of olefins.

Solubility
Sparingly soluble in water at 25°C 2.1E-5 g/L.

Notes
Air sensitive. Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
TRUSTED_SUSTAINABILITY
Melting Point 88°C to 90°C
Quantity 0.25 g
Beilstein 1630280
Sensitivity Air sensitive
Solubility Information Sparingly soluble in water at 25°C 2.1E-5g/L.
Optical Rotation +12.5° (c=4.6 in Benzene)
Formula Weight 498.55
Percent Purity 98%
Chemical Name or Material (+)-DIOP
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