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4-Bromo-1-butene, 97%

Product Code. 15473027
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Product Code. 15473027

Brand: Thermo Scientific Alfa Aesar A10977.18

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CAS: 5162-44-7 | C4H7Br | 135.004 g/mol

4-Bromo-1-butene is used in the preparation of 4-(3-butenyloxy)benzoic acid and largazole. It is also used in double alkylation of lactams followed by Grubbs ring-closing metathesis to yield gymnodimine. Further, it serves as a reagent in the preparation of dienehydrazides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
4-Bromo-1-butene is used in the preparation of 4-(3-butenyloxy)benzoic acid and largazole. It is also used in double alkylation of lactams followed by Grubbs ring-closing metathesis to yield gymnodimine. Further, it serves as a reagent in the preparation of dienehydrazides.

Solubility
Miscible with water, benzene, ether and ethanol.

Notes
Light sensitive. Store in a cool place. Incompatible with strong bases.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 5162-44-7
Molecular Formula C4H7Br
MDL Number MFCD00000258
InChI Key DMAYBPBPEUFIHJ-UHFFFAOYSA-N
Synonym 4-bromo-1-butene, 3-butenyl bromide, 1-butene, 4-bromo, 4-bromo-1-buten, 4-bromo-but-1-ene, homoallyl bromide, 1-bromo-3-butene, 4-bromobutene, 4-bromo-1 butene, sjphabijuh@
PubChem CID 21241
IUPAC Name 4-bromobut-1-ene

Specifications

Density 1.33
Boiling Point 98°C to 100°C
Flash Point 1°C
Refractive Index 1.463
Quantity 50 g
UN Number UN1993
Beilstein 1098377
Sensitivity Light sensitive
Solubility Information Miscible with water,benzene,ether and ethanol.
SMILES BrCCC=C
Molecular Weight (g/mol) 135.00
Formula Weight 135
Percent Purity 97%
Chemical Name or Material 4-Bromo-1-butene
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Product Identifier
  • 4-Bromo-1-butene
Signal Word
  • Danger
Hazard Category
  • Serious eye damage/eye irritation Category 2
  • Flammable liquid Category 2
  • Respiratory sensitiser Category 1
  • Skin sensitiser Category 1
  • Specific target organ toxicity Category 3
Hazard Statement
  • H225-Highly flammable liquid and vapour.
  • H317-May cause an allergic skin reaction.
  • H319-Causes serious eye irritation.
  • H334-May cause allergy or asthma symptoms or breathing difficulties if inhaled.
  • H335-May cause respiratory irritation.
Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P240-Ground/bond container and receiving equipment.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P342+P311-If experiencing respiratory symptoms: Call a POISON CENTER/doctor/ .
Supplemental information
  • MIXTURE LIST-Contains : 4-Bromo-1-butene

RUO – Research Use Only

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